Russell Hobby, general secretary of union NAHT, is set to take over as chief executive at Teach First.
Hobby is set to take over the social mobility charity in September when chief executive and founder Brett Wigdortz stands down.
Wigdortz announced his departure from the organisation he set up 15 years ago in January.
However, he will remain Teach First’s honorary president.
Hobby commented: "Over the last 15 years I have watched the Teach First movement grow from a handful of raw recruits to the national scale and influence it has today," he said.
"Yet it has never lost its focus on young people, their enormous potential and the power of teachers and leaders to change lives.
"I’m looking forward to building on all that has been achieved.”
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School food improvement programme Nourish is set to launch in Cumberland in 2026, working with schools to improve the quality and culture of food throughout the school day
A creative careers programme which aims to inspire young people to explore careers across the creative industries has reached 210,000 young people since 2023.